Substoichiometric radiochemical determination of silver with potassium ethyl xanthate in photofilm washings.

Ab Initio Modeling of Xanthate Adsorption on ZnS Surfaces

Modeling surface adsorption requires systems of hundreds of atoms. To model such systems at an ab initio level successfully, we need to avoid traditional quantum chemical methods. In the present work we have shown that density functional theory is a powerful modeling tool for large chemical systems especially in combinations with pseudopotentials This is validated by an initial study of ethyl a...

Synthesis, characterization, and luminescent properties of dinuclear gold(I) xanthate complexes: X-ray structure of [Au2(nBu-xanthate)2].

The synthesis and characterization of gold(I) complexes of butyl xanthate [Au(2)((n)()Bu-xanthate)(2)], 1, and ethyl xanthate [Au(2)(Et-xanthate)(2)], 2, are described. These complexes are readily prepared from the reaction between Au(THT)Cl (THT = tetrahydrothiophene) and the corresponding xanthate ligands as the potassium salts. The two xanthate complexes are characterized by (1)H NMR, IR, ma...

Electrochemistry of Copper Activation of Sphalerite and Potassium Isobutyl Xanthate (KIBX) Synthesized Collectors Adsorption

Catalytic Kinetic Determination of Silver through its Catalytic Effect on Congo Red-Peroxodisulphate Reaction

A kinetic-spectrophotometric procedure is reported for determination of trace amounts of Ag(I). This method is based on catalytic effect of silver ion on the oxidation of congo red by potassium peroxodisulphate at pH=3.4 and 30 oC in the presence of 1,10-phenanthroline as an activator. The reaction was followed spectrophotometrically by measuring the rate of change in absorbance ...

Selective separation of galena and sphalerite from pyrite-rich lead-zinc ores: A case study of the Kooshk mine, Central Iran

In this research, the selective flotation of galena and sphalerite minerals was evaluated from a pyrite-rich lead-zinc sample. An optimum mixture of selective collectors against pyrite and also organic/inorganic pyrite depressants was obtained in the flotation of galena and sphalerite by an experimental mixture design. The effect of different collectors and pH values were investigated in the ob...